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class="smal-hide"><span>發(fā)布時(shí)間：2020-06-16 10:06</span> <span>點(diǎn)擊：</span></p> </h6> <div id="vwkm0a6" class="wznr"><div> 一、VOC的界說(shuō)及損害現狀</div> <div> VOCS是指在必定條件下具有揮發(fā)性有機化合物的總稱(chēng)。揮發(fā)性有機化合物首要包含非甲烷總烴、含氧化合物、鹵代烴、含氮化合物、含硫化合物等。作為一個(gè)制造業(yè)大國，每年我國排放的VOC現已超越2000萬(wàn)t，其肯定排放量要比二氧化硫、氮氧化物以及粉塵的排放量都高，因而，操控揮發(fā)性有機物的排放對大氣環(huán)境是非常重要的。 <br /> <img alt="" src="/uploads/allimg/200616/1-200616102434215.jpg" style="width: 500px; height: 375px;" /></div> <div> 二、 VOC的管理辦法</div> <div> 醫藥化工行業(yè)在有機組成反響及離心精制、有機物儲罐無(wú)安排揮發(fā)等工況下會(huì )產(chǎn)生很多的有機揮發(fā)性廢氣。</div> <div> 1、 VOC的傳統管理辦法</div> <div> V0C不只來(lái)歷非常廣泛，其組成成分也非常復雜，常見(jiàn)的揮發(fā)性有機化合物包含烴類(lèi)、醇類(lèi)、醚類(lèi)等,即便關(guān)于同一物質(zhì)，因為其風(fēng)量、濃度的不同，所需的技能道路也不盡相同，因而,沒(méi)有一種技能能夠處理一切的V0C問(wèn)題。常用的VOC處理辦法稀有十種，其原理首要有收回有價(jià)值溶劑的收回技能和分化VOC分子的損壞技能兩大類(lèi)，實(shí)踐運用中更多選用組合式技能。</div> <div> 2、VOC的新式管理辦法</div> <div> 經(jīng)過(guò)選用催化燃燒和蓄熱式燃燒相結合的技能，用較少的能耗完結對VOC的完全處理;依據VOC本身的溶解度、沸點(diǎn)等理化性質(zhì)挑選適宜的吸附辦法。如挑選變溫吸附或變壓吸附進(jìn)行溶劑收回，收回時(shí)首要依據企業(yè)出產(chǎn)狀況來(lái)挑選相應的吸附辦法。</div> <div> （1）收回法首要有活性炭吸附、變壓吸附、冷凝法及膜分離技能，日前首要是經(jīng)過(guò)溫度、壓力、挑選性吸附劑和挑選性沒(méi)透膜等物理辦法來(lái)吸附有機揮發(fā)性物質(zhì)。</div> <div> （2）鏟除法有氧化、催化、生物氧化及集成技巧。其首要是經(jīng)過(guò)化學(xué)反響或生化反響，比方在熱、催化劑或微生物的作用下，把有害的有機物轉化成無(wú)害的CO2和HO。 </div> <div> 三、典型的VOC處理技能</div> <div> 1、吸附工藝技能</div> <div> 吸附技能是指吸附劑經(jīng)過(guò)物理結合的辦法或化學(xué)反響的辦法對有害物質(zhì)進(jìn)行吸附,然后到達凈化廢氣的意圖。在有機廢氣濃度較低時(shí)運用具有較好的作用，但不宜處理高濃度有機廢氣。假如處理高濃度有機廢氣，能夠用冷凝等辦法處理后，再運用吸附法對廢氣進(jìn)行處理。在吸附進(jìn)程中，吸附劑、設備、工藝、再生等都是其要害操控點(diǎn)。日前在VOC凈化進(jìn)程中常用的吸附劑有無(wú)機和有機吸附劑兩類(lèi)，吸附劑應挑選有巨大的表面積、杰出的挑選性、較強的再生性、較好的熱穩定性以及化學(xué)穩定性、較大的吸附容量等等?，F在市場(chǎng)上的吸附劑品種較多，常用的有活性炭、分子篩沸石等。吸附法對有機廢氣的凈化較為完全。在不運用深冷、高壓的手法下，可到達對有機成分收回運用的意圖，且該辦法無(wú)論是設備仍是操作都比較簡(jiǎn)</div> <div> 單，具有較高的主動(dòng)化程度，不會(huì )形成二次污染?；钚蕴课焦に嚨拈L(cháng)處適用于處理各種低濃度的污染物。在實(shí)踐運用中，活性炎的長(cháng)處為:賤價(jià)、低耗能經(jīng)濟、耐酸堿、耐熱以及具有很高的化學(xué)穩定性，并且活性炎在運用進(jìn)程中操作非常簡(jiǎn)潔，只需要與空氣相接就能夠發(fā)揮作用?？墒腔钚蕴恳泊嬖? -定的缺陷，比方吸附量較小，在運用進(jìn)程中簡(jiǎn)單呈現飽滿(mǎn)的現象;關(guān)于吸附劑的耗費比較大，且吸附才能不強。運用必定的時(shí)刻后會(huì )使吸附量變小，甚至失掉吸附才能。別的,吸附時(shí)存在吸附的專(zhuān)注性問(wèn)題，對混合氣體，吸附性會(huì )削弱，存在被吸附物質(zhì)的分子直徑與活性炭孔徑不匹配而導致的脫附現象。</div> <div> 2、吸收工藝技能</div> <div> 該吸收技能的原理是將有機廢氣和吸收劑進(jìn)行充沛的觸摸，然后把廢氣中有害的物質(zhì)吸附出來(lái),完結對廢氣的凈化處理，其首要是選用物理吸收或者是化學(xué)反響的辦法來(lái)完結。當完結有害物質(zhì)的吸附之后，再經(jīng)過(guò)解吸將吸附劑中的有害物質(zhì)鏟除,從面完結對吸附劑的清洗，然后進(jìn)行再生運用,較常用的吸收劑有酸性溶液、清水等。吸收工藝的優(yōu)勢是整個(gè)體系為閉路循環(huán)，除蒸汽冷凝水外無(wú)廢水、廢液排放，燕汽冷凝水可考慮歸納收回運用。該操控體系選用了先進(jìn)的操控理念，在正常平穩運轉的一起削減了人工操作，真實(shí)完結了無(wú)人值守、主動(dòng)運轉，在收回功率、可操作性、低能耗等方面均到達了國內先進(jìn)水平。</div> <div> 3、噴淋法工藝技能</div> <div> 該技能是指把有機廢氣抽人帶有噴淋體系的噴淋塔中,氣體經(jīng)過(guò)填料床后能夠均勻地、充沛與噴淋液進(jìn)行觸摸，依據廢氣中有害物質(zhì)的理化性質(zhì)，選用物理吸附的辦法或化學(xué)反響的辦法將污染物鏟除，然后使有機廢氣得到凈化。</div> <div> 4、冷凝工藝技能</div> <div> 在不同溫度以及壓力下。氣態(tài)的污染物具有不同的飽滿(mǎn)度，冷凝工藝便是依據該原理，經(jīng)過(guò)下降氣態(tài)污染物的溫度以及添加氣態(tài)污染物的壓力來(lái)完結有機物的凝聚,終究進(jìn)行凈化收回。關(guān)于制藥廠(chǎng)所產(chǎn)生的有機廢氣,要從源頭、中端以及結尾對其進(jìn)行全方位的歸納管理，并依據實(shí)踐工況挑選適宜的處理工藝技能。從源頭和進(jìn)程操控進(jìn)行定時(shí)檢測，若發(fā)現問(wèn)題應及時(shí)對其進(jìn)行處理，然后到達下降甚至根絕產(chǎn)生跑、冒、滴、潮的意圖;在出產(chǎn)進(jìn)程中，經(jīng)過(guò)對密閉的、一體化的技能以及設備的運用，削減有機廢氣的走漏，并對廢氣進(jìn)行搜集、分類(lèi)、處理。*終對廢氣結尾管理與歸納運用。當結尾廢氣中污染物質(zhì)量濃度較低時(shí)，關(guān)于能收回的廢氣，可經(jīng)過(guò)吸附對有機試劑進(jìn)行收回處理后再排放;關(guān)于沒(méi)有收回價(jià)值的廢氣來(lái)說(shuō)，可經(jīng)過(guò)多種技能，比方濃縮燃燒技能、等離子體技能或紫外光高檔氧化技能等凈化后合格排放;關(guān)于質(zhì)量濃度處于中等的有機廢氣，可經(jīng)過(guò)吸附將有機溶劑收回，然后經(jīng)過(guò)燃燒將廢氣凈化。關(guān)于高濃度VOC的廢氣，則能夠經(jīng)過(guò)冷凝、吸附等技能將有機溶劑收回。</div> </div> <p id="cztz">版權聲明：本網(wǎng)注明來(lái)源為“環(huán)亞環(huán)?！钡奈淖?、圖片內容，版權均屬本站所有，如若轉載，請注明本文出處：http://shahriardoes.com 。同時(shí)本網(wǎng)轉載內容僅為傳播資訊，不代表本網(wǎng)觀(guān)點(diǎn)。如涉及作品內容、版權和其它問(wèn)題，請與本網(wǎng)站聯(lián)系，我們將在及時(shí)刪除內容。</p> <p><br></p> <span id="gbbo8ms" class="czt"> <li id="tjyd"> 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